Product Identification
【Product Name】3,4,5-Trihydroxybenzoic acid 没食子酸
【CAS】149-91-7
【Formula】C7H6O5
【Molecular Weight】170.12
【EINECS】205-749-9
【RTECS】LW7525000
【RTECS Class】Agricultural Chemical and Pesticide; Mutagen; Reproductive Effector
【Merck】13,4366
【Beilstein/Gmelin】2050274
【Beilstein Reference】3-10-00-02070
Physical and Chemical Properties
【Appearance】Odorless white solid.
【Solubility in water】11 g/L
【Melting Point】251 - 252
【Boiling Point】501
【Vapor Pressure】7E-11 (25 C)
【Density】1.694 g/cm3
【pKa/pKb】4.40 (pKa)
【Partition Coefficient】.91
【Heat Of Vaporization】81.1 kJ/mol
【Heat Of Combustion】-2655 kJ/mol
【Usage】Manufac gallic acid esters, pyrogallol, inks, as photographic developer, in tanning, in dyeing, in testing for free mineral acids, dihydroxyacetone and alkaloids. Esters as antioxidants. Formerly as astringent, styptic.
First Aid Measures
【Ingestion】Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
【Skin】Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and Storage
【Storage】Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from light.
【Handling】Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Store protected from light.
Hazards Identification
【Inhalation】May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】Causes skin irritation.
【Eyes】Causes eye irritation. Exposure to solid may cause pain and redness. May cause chemical conjunctivitis.
【Ingestion】May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
【EC Risk Phrase】R 36/37/38
【EC Safety Phrase】S 26 36
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】Prolonged or repeated skin contact may cause dermatitis.
【Poison Class】4
Fire Fighting Measures
【Flash Point】271
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】This material is probably combustible.
Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and Reactivity
【Stability】Stable at room temperature in closed containers under normal storage and handling conditions.
【Incompatibilities】Strong oxidizing agents.
【Decomposition】Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.