Product Identification
【Product Name】1-Bromo-3-methoxybenzene
【Synonyms】3-Bromoanisole  间溴苯甲醚
【CAS】2398-37-0
【Formula】C7H7BrO
【Molecular Weight】187.04
【EINECS】219-264-5
【Beilstein/Gmelin】1524687
【Beilstein Reference】4-06-00-01043
【EC Class】dangerous for the environment

Physical and Chemical Properties
【Appearance】Clear very slight brown liquid.
【Solubility in water】Insoluble
【Melting Point】2℃
【Boiling Point】211℃
【Density】1.49 g/cm3 (20℃)
【Refractive Index】1.5635 (20℃)

First Aid Measures
【Ingestion】Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Get medical aid if irritation or symptoms occur.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
【Skin】Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical aid if symptoms occur.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid.

Handling and Storage
【Storage】Store in a cool, dry place. Keep container closed when not in use.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification
【Ingestion】May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
【Inhalation】May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】May cause skin irritation. The toxicological properties of this material have not been fully investigated.
【Eyes】May cause eye irritation. The toxicological properties of this material have not been fully investigated.
【EC Risk Phrase】R 52/53
【EC Safety Phrase】S 24/25

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Fire Fighting Measures
【Flash Point】95℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Cool containers with flooding quantities of water until well after fire is out.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.

Stability and Reactivity
【Disposal Code】2
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents - strong acids.
【Decomposition】Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.

Transport Information
【HS Code】2909 30 38