Product Identification
【Product Name】2-Bromopyridine
【Synonyms】2-Pyridyl bromide；2-溴吡啶
【CAS】109-04-6
【Formula】C5H4BrN
【Molecular Weight】158
【EINECS】203-641-6
【RTECS】US3850000
【RTECS Class】Other
【Beilstein/Gmelin】105789
【Beilstein Reference】5-20-05-00422
【EC Class】toxic, irritant

Physical and Chemical Properties
【Appearance】Clear slight brown liquid.
【Solubility in water】Slightly soluble
【Melting Point】-40.1℃
【Boiling Point】192℃
【Vapor Pressure】0.00153 (-40℃)
【Density】1.167 g/cm3 (15℃)
【pKa/pKb】13.21 (pKb)
【Heat Of Vaporization】54.40 kJ/mol
【Heat Of Combustion】-2623 kJ/mol
【Refractive Index】1.5734 (20℃)

First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage
【Storage】Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
【Handling】Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or flames.

Hazards Identification
【Inhalation】Harmful if inhaled. May cause respiratory tract irritation. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest.
【Skin】May cause skin irritation. May be fatal if absorbed through the skin. May cause cyanosis of the extremities.
【Eyes】Causes eye irritation.
【Ingestion】Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
【Hazards】Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will sp along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers.
【EC Risk Phrase】R 10 23/24/25 36
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】2929

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact may cause conjunctivitis.
【Poison Class】2

Fire Fighting Measures
【Flash Point】90.6℃
【Autoignition】>400℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
【Fire Potential】HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool. A vapor suppressing foam may be used to reduce vapors.

Stability and Reactivity
【Disposal Code】2
【Incompatibilities】Acid chlorides, strong acids, strong oxidizing agents.
【Stability】Stable under normal temperatures and pressures.
【Decomposition】Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide, nitrogen.
【Combustion Products】Fire will produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】2929
【Hazard Class】6.1
【Packing Group】I; II
【HS Code】2933 39 99